Disclaimer

Deep Carbon Cycle is no longer an active organization or initiative. This website serves solely as a historical reference and archive of its previous research, projects, and contributions to the field. The information provided here reflects the work done during its active years, but the project is no longer operational.

Volcanoes: Nature’s Carbon Release Valves

Volcanoes are more than just fiery spectacles—they play an essential role in regulating the Earth’s carbon cycle and climate. While we often think of volcanic eruptions as dramatic events that disrupt local environments, they are also a crucial part of the planet’s natural system for controlling carbon levels. These mighty forces of nature act as carbon release valves, helping to regulate the carbon stored deep within the Earth’s interior and influencing global temperatures over long periods of time. In this post, we’ll explore how volcanoes contribute to Earth’s carbon balance, their impact on climate, and their critical role in stabilizing our planet’s atmosphere.

The Role of Volcanoes in the Carbon Cycle
The Earth’s carbon cycle is a complex system involving the movement of carbon between the atmosphere, oceans, land, and the Earth’s interior. Carbon is naturally stored deep within the Earth’s mantle, and through the process of volcanic outgassing, volcanoes release carbon dioxide (CO2) into the atmosphere. This release is part of the deep carbon cycle, which operates over millions of years to maintain a balance between carbon stored in the Earth’s interior and the carbon in the atmosphere.

When tectonic plates collide and subduct beneath one another, carbon-rich materials are transported deep into the mantle. There, they can be stored for long periods, sometimes for millions of years. When the Earth’s tectonic plates shift, volcanic eruptions bring some of that carbon back to the surface in the form of CO2, where it is released into the atmosphere.

Why Volcanoes Are Essential for Climate Regulation
Volcanoes play a critical role in regulating Earth’s climate by influencing the levels of CO2 in the atmosphere. Carbon dioxide is a greenhouse gas, meaning it traps heat in the Earth’s atmosphere and contributes to the planet’s overall temperature. Volcanic eruptions release CO2, which can temporarily raise atmospheric carbon levels. However, this process is part of a long-term balance. Over millions of years, the release of carbon through volcanic eruptions has helped regulate Earth’s temperature and climate stability.

While individual eruptions may cause short-term warming, they can also have cooling effects. Large eruptions can release particulate matter such as ash and sulfur dioxide, which can reflect sunlight and cool the planet for a period. These cooling effects are often temporary, lasting from months to a few years, but they demonstrate how volcanoes are a part of the Earth’s natural climate regulation system.

The Impact of Volcanic Activity on Atmospheric CO2
Volcanic activity has long been a primary mechanism for transferring carbon from the Earth’s interior to the atmosphere. Over geological timescales, the Earth’s volcanic activity contributes to a steady release of carbon dioxide. While volcanic eruptions may seem sporadic, the cumulative effect of volcanic activity over millions of years has had a significant impact on atmospheric CO2 levels.

Interestingly, the total amount of CO2 released by volcanic eruptions is relatively small when compared to human-caused emissions from burning fossil fuels. However, the long-term, cyclical nature of volcanic carbon release plays a stabilizing role in the carbon cycle. Without volcanic eruptions, the Earth would have a much harder time maintaining the balance of carbon needed for a stable climate.

Volcanoes and the Earth’s Natural Thermostat
Volcanoes serve as a type of natural thermostat for Earth’s climate. When carbon dioxide is released into the atmosphere by volcanic eruptions, it can contribute to the greenhouse effect, warming the planet. However, this is a slow process, and over time, the Earth’s natural systems, including the deep carbon cycle, help regulate the release of carbon, ensuring that global temperatures don’t rise too quickly.

The balance between carbon storage in the Earth’s interior and the carbon released by volcanoes has helped maintain relatively stable temperatures for most of Earth’s history. Large volcanic events can cause temporary fluctuations in the climate, but over long periods, the natural cycle ensures that Earth remains habitable.

Volcanoes and Human Influence on the Carbon Cycle
While volcanic activity is a natural process that has been occurring for millions of years, human activities are now dramatically altering the carbon cycle. The burning of fossil fuels, deforestation, and industrial activities have caused a sharp increase in atmospheric CO2, overwhelming the Earth’s natural systems, including volcanic outgassing.

In recent decades, the increase in atmospheric carbon due to human activity has led to rising global temperatures and climate change. While volcanoes continue to release carbon, the amount of CO2 released by human activities far exceeds what is emitted by volcanic eruptions. Understanding the role of volcanoes in the carbon cycle is essential for recognizing the natural processes that contribute to climate regulation and the impact of human-caused emissions.

How Scientists Study Volcanoes and Carbon Emissions
Scientists study volcanic emissions to understand how much carbon dioxide is being released into the atmosphere and how it affects global carbon levels. Researchers use various methods to measure volcanic gases, including direct sampling during eruptions, satellite imaging, and analysis of volcanic rock samples. By studying volcanic activity and its impact on atmospheric CO2, scientists can better understand the long-term effects of volcanic outgassing on Earth’s climate.

In addition to monitoring current volcanic emissions, scientists also examine historical volcanic data to learn about past climate changes. By studying past eruptions and the release of carbon, scientists can gain insights into how volcanic activity has influenced global temperatures and climate stability over geological timescales.

Conclusion: Volcanoes: Nature’s Carbon Release Valves
Volcanoes are a critical component of the Earth’s natural carbon cycle, acting as nature’s carbon release valves. By releasing carbon dioxide from the Earth’s interior, volcanoes help regulate atmospheric CO2 levels and influence Earth’s climate. While individual eruptions may have short-term effects on global temperatures, the long-term impact of volcanic activity has been essential for maintaining a stable climate. Understanding how volcanoes function within the carbon cycle can help us better appreciate their role in shaping Earth’s climate and why they remain vital to the stability of our planet.

Understanding The Earth’s Hidden Engine

Earth is a dynamic and ever-changing planet, shaped by a variety of natural processes. While many people are familiar with surface-level phenomena like the water cycle or weather patterns, there’s a much deeper, less visible system that plays a critical role in maintaining the planet’s carbon balance. Often referred to as Earth’s “hidden engine,” the deep carbon cycle is responsible for regulating long-term carbon storage, atmospheric CO2 levels, and, ultimately, the stability of Earth’s climate. In this post, we will explore how this crucial cycle operates beneath our feet and why it matters so much to the health of our planet.

The Key Processes of the Deep Carbon Cycle:

  1. Carbon Subduction:
    Carbon from the surface is drawn into the Earth’s interior through subduction zones, where tectonic plates meet. One plate slides beneath another, carrying carbon-rich materials such as carbonates and organic matter deep into the mantle. These materials are stored in the mantle for millions of years before being released through volcanic eruptions.

  2. Volcanic Outgassing:
    Volcanoes play a crucial role in the deep carbon cycle by acting as release valves for carbon stored deep within the Earth. When tectonic plates move and magma rises, carbon dioxide (CO2) trapped in the mantle is released into the atmosphere through volcanic eruptions. This release of CO2 is a natural mechanism that regulates atmospheric carbon levels over time.

  3. Plate Tectonics and Carbon Movement:
    The movement of tectonic plates is central to the deep carbon cycle. When plates collide and one is forced into the mantle, carbon is carried deep within the Earth. Over time, this carbon can remain stored for millions of years before it is released back into the atmosphere through volcanic activity. This process of subduction and volcanic eruption maintains a balance between the Earth’s interior and surface carbon.

Why Is the Deep Carbon Cycle Important?
The deep carbon cycle is critical for maintaining the Earth’s climate and supporting life. By controlling the flow of carbon between the Earth’s surface and interior, this cycle helps regulate global temperatures, prevent climate extremes, and ensure the stability of atmospheric CO2 levels. Without the deep carbon cycle, carbon could accumulate in the atmosphere or be trapped in the Earth’s crust, leading to drastic shifts in climate.

The Role of Volcanic Activity in Climate Regulation:
Volcanic eruptions are one of the primary ways that carbon is transferred from the Earth’s interior to the surface. However, volcanic activity does more than just release carbon dioxide; it can also influence short-term climate patterns. Large volcanic eruptions eject particles into the atmosphere, which reflect sunlight and can cause temporary cooling effects. This cooling influence, combined with the long-term release of CO2, helps maintain climate stability on a global scale.

How the Deep Carbon Cycle Affects Earth’s Climate:
While the deep carbon cycle operates on a geological timescale, its impact on Earth’s climate is significant. The amount of carbon dioxide in the atmosphere directly affects global temperatures, and the deep carbon cycle plays a key role in maintaining this balance. When volcanic activity releases CO2 into the atmosphere, it can trigger periods of warming. Conversely, when volcanic activity decreases, atmospheric CO2 levels fall, leading to cooling periods. This process helps to stabilize the Earth’s climate over millions of years.

Human Influence on the Deep Carbon Cycle:
While the deep carbon cycle operates naturally over millions of years, human activities are altering the carbon balance on a much shorter timescale. The burning of fossil fuels, deforestation, and industrial activities are releasing vast amounts of CO2 into the atmosphere at an unprecedented rate, disrupting the Earth’s natural carbon cycle. This increase in atmospheric carbon is accelerating climate change and shifting the balance of carbon on Earth. Understanding the deep carbon cycle is essential for developing strategies to mitigate these impacts and restore equilibrium.

How Scientists Study the Deep Carbon Cycle:
Studying the deep carbon cycle is a complex and ongoing process. Scientists use a variety of tools to investigate how carbon moves through the Earth’s interior, including seismic imaging, volcanic gas measurements, and laboratory simulations of high-pressure conditions. By examining volcanic rocks, mineral formations, and gas emissions, researchers can learn more about how carbon is stored, transported, and released within the Earth. This research helps scientists predict how the deep carbon cycle might evolve in the future and how it could impact global climate patterns.

Conclusion:
The deep carbon cycle is truly Earth’s hidden engine, working behind the scenes to regulate carbon storage, atmospheric CO2 levels, and climate stability. This natural process is essential for maintaining the conditions necessary for life on Earth. As human activities continue to disrupt the carbon balance, understanding the deep carbon cycle becomes more important than ever. By studying this hidden engine, we can gain a deeper understanding of our planet’s systems and better prepare for the challenges of climate change.

Workshop Delivers New Estimate of Global Carbon Degassing

Twenty-eight DCO members came together from 29 April  –  4 May, 2018 at the Carnegie Institution for Science in Washington, DC to calculate a new estimate of global carbon dioxide (CO2) degassing from large volcanic emitters, small volcanic sources and diffuse degassing from volcanic regions. The synthesis of massive amounts of data was successfully tackled through a hands-on approach. Science talks were interspersed with breakout sessions, followed by more of the same.  “It was the most productive workshop I have ever attended,” said Terry Plank, DCO Executive Committee member and Reservoirs and Fluxes Science Community member (Columbia University, USA), “and should serve as a model for others to come.”

The DECADE synthesis workshop group attendees came prepared with a wealth of available volcanic emissions data they used to create a new global estimate.  Their work was exhaustive, with some of the highlights provided below.

The attendees evaluated emissions from subaerial volcanoes with active gas plumes to produce an updated and improved estimate of global SO2 flux. This quantity was then combined with their best present knowledge of C/S ratios in the plumes of those volcanoes to derive a corresponding emission of volcanogenic carbon.

They accounted for different types of emitters, including passively degassing volcanoes, explosive eruptions, and effusive eruptions and distinguished between arc and non-arc volcanic sources. They compiled data covering 11 years from 2005 to 2015, and used information from long-term monitoring from space (mostly OMI satellite) and ground (mostly NOVAC network), as well as short-term campaign data and reports from the literature. The group also identified the need for further comparisons between satellite- and ground-based flux observations and the lack of C/S data, in particular for large eruptions.

To improve estimates from small volcanic sources, they assembled a new compilation of worldwide data from more than 40 volcanoes that emit small CO2 plumes and carefully selected appropriate volcanoes to include in the extrapolation.  The group then individually reviewed more than 750 volcanoes from across the globe that could potentially host small plumes and categorized their emissions as ‘magmatic’, ‘hydrothermal’, or ‘none’.  Said Tobias Fischer (University of New Mexico, USA), one of the initial workshop organizers, “When complete, this analysis will be the most rigorous and transparent estimate of global CO2 emissions from small volcanic sources yet determined.”

Attendees also delivered the first estimate of global carbon dioxide (CO2) degassing from diffuse degassing sources of volcanoes based on the published data reported in MaGa, a recent catalogue of diffuse gas emissions around the world, while also addressing uncertainties of the data.  Other attendees analyzed subduction data that were providing insights into volatile cycling on both regional and global scales, while others considered what could be learned from the rock record.

Overall, the results from this workshop will provide new and more rigorously constrained global deep carbon emission estimates, new insights into the fate of subducted carbon and new methods for estimating volcanic CO2 fluxes through time using petrologic parameters. The workshop also highlighted the need for continued multi-disciplinary efforts in the area of volcanic and tectonic degassing to advance understanding of the transfer of volatiles between Earth’s reservoirs.

Job Opening: Postdoctoral Research Associate

Applications were invited for a highly qualified and motivated postdoctoral research scientist with a geologic background in computational geophysical fluid dynamics, whose primary responsibility will be to develop new codes to study carbon transport in numerical models of fluid flow in subduction zones.

Melting Temperature of Earth’s Mantle Depends on Water

A joint study between Carnegie and the Woods Hole Oceanographic Institution has determined that the average temperature of Earth’s mantle beneath ocean basins was about 110 degrees Fahrenheit (60 Celsius) higher than previously thought, due to water present in deep minerals. The results are published in Science.

Earth’s mantle, the layer just beneath the crust, was the source of most of the magma that erupts at volcanoes. Minerals that make up the mantle contain small amounts of water, not as a liquid, but as individual molecules in the mineral’s atomic structure.  Mid-ocean ridges, volcanic undersea mountain ranges, are formed when these mantle minerals exceed their melting point, become partially molten, and produce magma that ascends to the surface. As the magmas cool, they form basalt, the most-common rock on Earth and the basis of oceanic crust. In these oceanic ridges, basalt can be three to four miles thick.

Studying these undersea ranges can teach scientists about what was happening in the mantle, and about the Earth’s subsurface geochemistry.

One longstanding question has been a measurement of what’s called the mantle’s potential temperature. Potential temperature was a quantification of the average temperature of a dynamic system if every part of it were theoretically brought to the same pressure. Determining the potential temperature of a mantle system allows scientists better to understand flow pathways and conductivity beneath the Earth’s crust. The potential temperature of an area of the mantle can be more closely estimated by knowing the melting point of the mantle rocks that eventually erupt as magma and then cool to form the oceanic crust.

In damp conditions, the melting point of peridotite, which melts to form the bulk of mid-ocean ridge basalts, was dramatically lower than in dry conditions, regardless of pressure. This means that the depth at which the mantle rocks start to melt and well up to the surface will be different if the peridotite contains water, and beneath the oceanic crust, the upper mantle was thought to contain small amounts of water—between 50 and 200 parts per million in the minerals of mantle rock.

So lead author Emily Sarafian of Woods Hole, Carnegie’s Erik Hauri, and their team set out to use lab experiments in order to determine the melting point of peridotite under mantle-like pressures in the presence of known amounts of water.

“Small amounts of water have a big effect on melting temperature, and this was the first time experiments have ever been conducted to determine precisely how the mantle’s melting temperature depends on such small amounts of water,” Hauri said.

They found that the potential temperature of the mantle beneath the oceanic crust was hotter than had previously been estimated.

“These results may change our understanding of the mantle’s viscosity and how it influences some tectonic plate movements,” Sarafian added.

The study’s other co-authors are Glenn Gaetani and Adam Sarafian, also of Woods Hole.

This research was funded by the National Science Foundation and the Woods Hole Oceanographic Institution’s Deep Ocean Exploration Institute.

Live Blog: Trail by Fire 1.5 expedition to South America

The atmosphere that allows our planet to sustain life formed from gases emitted by volcanoes early in Earth’s history. These volatile elements are constantly recycled back into the deep Earth at subduction zones, where tectonic plates sink into the mantle. During this process the sinking plate was subjected to increasing heat and pressure, and releases volatiles. These volatiles, once added to the mantle, induce melting and fuel volcanic explosions, completing the cycle. While this depiction of the earth’s giant recycling factory was well established conceptually, they do not know how efficient it is. They can estimate how much goes in, but have little idea what proportion was released back to the atmosphere, and what proportion remains trapped at depth. This question was crucial if they want to understand how our atmosphere formed and our planet became able to sustain life. In the present-day context, characterizing how much gas comes out of the giant recycling factory was also key to understanding volcanic effects on climate, volcanic emissions being significant – but poorly constrained – parameters in current climate models..

Their team of early career volcanologists was conducting expeditions to the South American Andes. Their objective was to provide the first accurate and large-scale estimate of the flux of volatile species (H2O, H2, CO2, CO, SO2, H2S, HCl, HF, and more) emitted by volcanoes of the Nazca subduction zone. The journey was taking us across half a continent, from the giant volcanoes of Ecuador through the altiplanoes of Peru and to the Southern tip of Chile, traveling on some of the Earth’s highest roads, and climbing some of the Earth’s tallest volcanoes.

Deep Mantle Chemistry Surprise: Carbon Content not Uniform

Even though carbon was one of the most abundant elements on Earth, it was actually very difficult to determine how much of it exists below the surface in Earth’s interior.

Research by Deep Carbon Observatory scientists Marion Le Voyer, Erik Hauri (Carnegie Institution for Science, USA), Katherine Kelley (University of Rhode Island, USA) and Elizabeth Cottrell (Smithsonian Institution, USA) has doubled the world’s known finds of mantle carbon. Their findings, based on analyses of crystals containing mantle magma samples, are published in Nature Communications.

Overall, there was a lot about carbon chemistry that takes place below Earth’s crust that scientists still don’t understand. In particular, the amount of carbon in the Earth’s mantle has been the subject of hot debate for decades. This topic was of interest because the amount of carbon present in the mantle underpins our planet’s geological processes, including triggering volcanic activity and sustaining the biosphere. It also affects our atmosphere when carbon dioxide gas was released by eruptions; volcanic eruptions played a large role in pre-historic climate variations.

But it’s difficult to measure the amount of carbon that exists below the Earth’s surface. Scientists can study the igneous rocks that formed when mantle melts, called magma, rose to the surface, erupted as lava, and hardened again to create a rock that was called basalt. However, the process of ascent and eruption releases almost all the magma’s carbon as carbon dioxide gas, which makes the erupted basaltic rocks poor indicators of the amount of carbon that was in the magmas from which they formed.

“This is how explosive eruptions happen,” Hauri explained. “The sudden catastrophic loss of gas that, before the eruption, was dissolved into the magma at high pressure, but during eruption has nowhere else to go, leaving no post-eruption trace in the hardened basalt of the amount carbon once present.”

But Le Voyer, Hauri, and their team analyzed some basalt samples from the equatorial mid-Atlantic ridge that contained previously unstudied tiny magmatic inclusions, small pockets of pure magma that were completely trapped inside solid crystals that protected them from degassing during magma ascent and eruption. Analysis showed that these inclusions had trapped their original carbon content before being erupted on the seafloor.

“This is only the second time that samples of magma containing their original carbon content have ever been found and analyzed, doubling our knowledge of the region’s carbon chemistry,” Hauri said.

The very first samples containing their original carbon were also revealed at Carnegie, by Hauri and Brown University professor Alberto Saal, in 2002. Those samples came from the Pacific seafloor. Comparison of the data for these two samples revealed that the mantle’s carbon content was much less uniform than scientists had previously predicted, varying by as much as two orders of magnitude in different parts of the mantle.

“Our discovery that mantle carbon has a more complex distribution than previously thought has many implications for how mantle processes may vary by location,” added Le Voyer, who conducted this research as a postdoc at Carnegie and was now at the University of Maryland.

Measuring Volcanic Eruptions from Space: Uniting Geophysical and Geochemical Data

When volcanoes erupt, they spew lava, ash, and gas into the atmosphere and over the surrounding landscape. The impacts of volcanic eruptions in populated areas are well documented, since scientists can monitor gas emissions and collect physical samples with relative ease. However, a significant fraction of Earth’s volcanoes are remote, making direct observation challenging.

Some researchers have therefore turned to space-based techniques, collecting data from satellites. In a new paper published in the journal Nature Communications, DCO collaborators Brendan McCormick Kilbride, Marie Edmonds (both at the University of Cambridge, UK), and Juliet Biggs (University of Bristol, UK), analyzed several sets of satellite data in order to reconcile, for the first time, geophysical and geochemical models of magma composition [1].

“We’ve known for some time that when many volcanoes erupt we see a change in elevation, like the volcano has deflated, and we can measure this change using satellite observations,” said Edmonds, co-Chair of DCO’s Reservoirs and Fluxes Community. “We also know that volcanic eruptions produce gas plumes rich in sulfur dioxide, which we can also measure from space. However, what’s been a bit of a mystery is how these two datasets fit together. We couldn’t spot a pattern.”

By measuring how much a volcano deforms throughout an eruption, scientists can make an estimate of the volume of material previously contained within the magma chamber. These measurements, however, were at odds with the mass of sulfur dioxide measured in the erupted gas plume.

“We were seeing way more sulfur dioxide than we would expect for the volume of materials expelled during an eruption,” said first author McCormick.

The team therefore began modeling what was going on beneath the surface. They found that if more gases like sulfur dioxide and carbon dioxide are present in magma, they change its physical properties. Magmas with high concentrations of these volatiles are not homogenous. Instead, the gases clump together, creating bubbles. These bubbly, spongy magmas are a lot more compressible than magmas without bubbles, partially explaining why many large eruptions rich in sulfur dioxide show only limited changes in ground deformation.

The authors also suggest that in eruptions with huge gas emissions, a fraction of pure gas could collect at the top of the magma chamber prior to eruption making the ratio of erupted gas to eruption volume even larger.

“What we’ve done here is build a model of volcanic eruptions that could explain several aspects of volatile rich magmas,” added McCormick. “We’ve shown that our model is consistent with several datasets. If we can confirm this relationship between sulfur dioxide output and eruption volume, we come closer to being able to use satellite data alone to investigate some of Earth’s most remote volcanoes.”

“These data also tell us a lot about the Earth system,” added Edmonds. “As we refine our model, and integrate data from DCO’s DECADE volcano monitoring stations, we’ll generate a much more accurate picture of deep volatile cycles, including the deep carbon cycle.”

Earth’s Largest Diamonds Form in Metal-bearing Part of Earth’s Mantle

Super-deep diamonds, which form more than 380 km deep in Earth’s mantle, were invaluable tools for deep carbon scientists.

Super-deep diamonds, which form more than 380 km deep in Earth’s mantle, were invaluable tools for deep carbon scientists. Not only do they harbor clues about how they formed and therefore the reactions taking place inside Earth, they also trap small samples of mantle minerals, so-called inclusions, within their carbon crystal structure as they grow. These tiny samples of Earth’s deep interior from the region where the diamond forms were preserved under high pressure within a super-strong, unreactive diamond shell.

Many super-deep diamonds were small, have poor clarity, and were not generally used as gemstones. However, in a paper published in the journal Science, a team of researchers led by Evan Smith of the Gemological Institute of America (GIA) and including Deep Carbon Observatory DMGC (Diamonds and Mantle Geodynamics of Carbon) collaborators Steven Shirey (Carnegie Institution for Science, USA) and Fabrizio Nestola (Università degli Studi di Padova, Italy), suggests giant gemstone diamonds, like the 3106 carat Cullinan, were super-deep diamonds formed under special mantle conditions [1].

Co-author Professor Fabrizio Nestola explains the method of X-ray diffraction at the University of Padova, Italy. This method was used to first identify the presence of cohenite (an iron-nickel carbide) within the metallic inclusions. (credit Chiara Anzolini and Fabrizio Nestola)

When gem diamonds were polished and cut, expert diamond cutters often remove sections of the stones with inclusions. These offcut diamond pieces were not normally made available to scientists, and were usually considered waste, but the team made special efforts to get their hands on some.

“The project started with our collaborators at the GIA who have the opportunity to observe a number of large gem diamonds and have access to some of their offcut pieces,” said Shirey. “Evan Smith, a GIA postdoctoral researcher had a hypothesis that large diamonds could form deep in the mantle from metallic liquid, but we needed to the samples to figure it out.”

When they analyzed the offcuts, the team discovered multi-mineral metallic inclusions containing iron-nickel metal, an iron-carbide mineral known as cohenite, and the iron-sulfide mineral pyrrhotite. There were also traces of fluid methane and hydrogen in the thin space between the mineral phases and the encasing diamond. At the original pressure and temperature deep in Earth’s mantle, the composition of these multi-mineral inclusions suggested to the research team that a much larger mass of molten metallic liquid existed from which pure carbon crystallized to form diamonds. As each diamond grew, small droplets of the metallic liquid got trapped. As the diamonds were brought to Earth’s surface by volcanic eruption, the liquid droplets crystallized to the individual minerals.

“My motivation in this work was to solve this long-standing mystery about how these especially large and alluring diamonds form,” said Smith. “Everything about them suggests they form in a special way and that means they might tell us something new about the behavior of mantle carbon. In this research I was chasing an idea that I published a couple years ago, that the low nitrogen content and large size of these (CLIPPIR) diamonds might be linked to metallic iron in the mantle. I was thrilled when I started finding the first few inclusions. With the expertise of everyone involved we saw the observations unfold into an amazing story from the deep Earth.”

As well as diamonds with only the metal inclusions, the team found additional similar diamonds with silicate mineral inclusions –that coexisted with smaller amounts of metal. This assemblage suggests that all the metal-containing diamonds formed between 360 and 750km deep inside Earth. This was much deeper than most other gem diamonds, which form in the lower part of continental tectonic plates at depths of 150–200 km.

These two observations together show not only that Earth’s largest gemstone diamonds form extremely deep in the mantle, but also in regions of the mantle with metallic iron, the first time these aspects of the largest gem diamonds have been recognized.

“The idea of metallic iron in the silicate mantle at far shallower levels than Earth’s iron core , is something Earth scientists have expected for a while,” said Shirey. “A number of experiments and simulations predicted it, but now we have physical evidence that this is the case.”

Previous experiments and theory suggested for many years that small amounts of metallic iron existed in parts of the deep mantle below about 250 km depth. Though it’s still unclear how much metallic iron was present in the lower mantle, this was a key observation for understanding of Earth and the conditions under which it formed and evolved. Because the metallic liquid at these pressures and temperatures contains carbon and hydrogen it plays a hitherto undetected role in the geochemical cycles of these elements in the deep mantle.

“This result provides a direct link between diamond formation and deep mantle conditions, addressing a key goal of the Deep Carbon Observatory,” said DCO Executive Director Robert Hazen (Carnegie Institution for Science, USA). “The fact that it was made possible by a hugely successful collaboration between Diamonds and Mantle Geodynamics of Carbon group and the Gemological Institute of America was also very exciting, highlighting the importance of academic connections with industry and their important role in providing postdoctoral funding and the key specimens for this research.”

New Special Issue of Lithos: The Nature of Diamonds and Their Use in Earth’s Study

The 15 November 2016 edition of the journal Lithos delves into the role of natural diamonds in deep Earth research.

Titled “The nature of diamonds and their use in Earth’s study,” the 15 November 2016 edition of the journal Lithos delves into the role of natural diamonds in deep Earth research. This special issue was edited by DCO scientists involved the Reservoirs and Fluxes initiative, Diamonds and the Mantle Geodynamics of Carbon (DMGC).

This special issue of Lithos was compiled in recognition of the second International Diamond School, which took place in January 2015 in Bressanone, Italy. The Deep Carbon Observatory and the Gemological Institute of America sponsored the school, which brought together more than 80 graduate students and postdocs from around the world. Many of the students of the school are authors in the special issue.

Fabrizio Nestola (Università degli Studi di Padova, Italy), Matteo Alvaro (Università degli Studi di Pavia, Italy), Graham Pearson (University of Alberta, Canada), and Steven Shirey (Carnegie Institution for Science, USA) edited a selection of 30 original research articles from 134 authors for the issue. The papers cover four main research areas: geochemistry, diamond forming fluids, and diamond origin sources; geothermo-barometry and geochronology of diamonds; super-deep diamonds, carbonado-like diamonds and diamondites; and innovative methods for the investigation of diamonds.

 

CONTENTS

The nature of diamonds and their use in earth’s study F. Nestola, M. Alvaro, D.G. Pearson, S.B. Shirey